Open AccessStructures of bromoalkanes' photodissociation in solution by means of ultrafast extended x-ray absorption fine-structure spectroscopy
Author(s) -
Dmitri A. Oulianov,
I. V. Tomov,
Alexander Dvornikov,
P. M. Rentzepis
Publication year - 2002
Publication title -
proceedings of the national academy of sciences of the united states of america
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.011
H-Index - 771
eISSN - 1091-6490
pISSN - 0027-8424
DOI - 10.1073/pnas.192447199
Subject(s) - cyclohexane , photodissociation , absorption (acoustics) , spectroscopy , ultrashort pulse , absorption spectroscopy , photochemistry , chemistry , x ray absorption fine structure , analytical chemistry (journal) , materials science , optics , laser , organic chemistry , physics , quantum mechanics , composite material
The structures of initial and final products of bromoalkanes' photodisociation reaction in cyclohexane solution have been measured with a bond length accuracy of 0.02 A by means of ultrafast time-resolved extended x-ray absorption fine structure spectroscopy. The photoredaction mechanism is also discussed.