Dynamic combinatorial synthesis of a catenane based on donor–acceptor interactions in water | Zendy

Ho Yu AuYeung | Zendy; G. Dan Pantoş | Zendy; Jeremy K. M. Sanders | Zendy

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Dynamic combinatorial synthesis of a catenane based on donor–acceptor interactions in water

Author(s) -

Ho Yu AuYeung,

G. Dan Pantoş,

Jeremy K. M. Sanders

Publication year - 2009

Publication title -

proceedings of the national academy of sciences

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.011

H-Index - 771

eISSN - 1091-6490

pISSN - 0027-8424

DOI - 10.1073/pnas.0809934106

Subject(s) - catenane , acceptor , chemistry , template , yield (engineering) , ring (chemistry) , electron donor , ionic bonding , block (permutation group theory) , combinatorial chemistry , nanotechnology , materials science , ion , organic chemistry , molecule , catalysis , mathematics , physics , geometry , metallurgy , condensed matter physics

A new type of neutral donor-acceptor [2]-catenane, containing both complementary units in the same ring was synthesized from a dynamic combinatorial library in water. The yield of the water soluble [2]-catenane is enhanced by increasing either building-block concentrations or ionic strength, or by the addition of an electron-rich template. NMR spectroscopy demonstrates that the template is intercalated between the 2 electron-deficient naphthalenediimide units of the catenane.

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