Space–time thermodynamics of the glass transition
Author(s) -
Mauro Merolle,
Juan P. Garrahan,
David Chandler
Publication year - 2005
Publication title -
proceedings of the national academy of sciences
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.011
H-Index - 771
eISSN - 1091-6490
pISSN - 0027-8424
DOI - 10.1073/pnas.0504820102
Subject(s) - statistical physics , entropy (arrow of time) , action (physics) , space (punctuation) , phase transition , glass transition , trajectory , distribution function , phase space , dynamical heterogeneity , thermodynamics , physics , mathematics , computer science , quantum mechanics , polymer , nuclear magnetic resonance , operating system
We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these distributions where the entropy of trajectory space is subextensive in time. These low action tails are a consequence of dynamic heterogeneity and an indication of phase coexistence in trajectory space. The glass transition, where the system falls out of equilibrium, is then an order-disorder phenomenon in space-time occurring at a temperature T(g), which is a weak function of measurement time. We illustrate our perspective ideas with facilitated lattice models and note how these ideas apply more generally.
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