Gold-Loaded Organic/Inorganic Nanocomposite Honeycomb Membranes
Author(s) -
Kok Hou Wong,
Thomas P. Davis,
Christopher BarnerKowollik,
Martina H. Stenzel
Publication year - 2006
Publication title -
australian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.319
H-Index - 77
eISSN - 1445-0038
pISSN - 0004-9425
DOI - 10.1071/ch06173
Subject(s) - copolymer , micelle , nanocomposite , polystyrene , colloidal gold , chemical engineering , materials science , nanoparticle , polymer chemistry , polymerization , porosity , membrane , self assembly , chemistry , organic chemistry , nanotechnology , polymer , composite material , aqueous solution , engineering , biochemistry
RAFT polymerization was used to prepare polystyrene ? poly(4-vinyl pyridine) block copolymers, PSn-b-P(4VP)m. Well-defined block copolymers were obtained despite some indications of hydrolysis of the RAFT endgroup during synthesis. The block copolymer PS70-b-P(4VP) 55 was self-assembled into micellar structures in dichloromethane, leading to nanoparticles with hydrodynamic diameters of 70 nm. The micelles were loaded with HAuCl4 and, upon reduction, micellar gold-containing nanoparticles with hydrodynamic diameters of 240 nm were obtained. These nanoparticles were employed in the preparation of honeycomb-structured porous films by means of the breath figures technique to yield gold nanocomposites with a hexagonal porous array. © CSIRO 2006
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