Open AccessTransport properties of topologically non-trivial bismuth tellurobromides BinTeBr
Author(s) -
Falk Pabst,
Dean Hobbis,
Noha Alzahrani,
Hsin Wang,
Igor P. Rusinov,
Eugene V. Chulkov,
Joshua Martin,
Michael Ruck,
George S. Nolas
Publication year - 2019
Publication title -
journal of applied physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.699
H-Index - 319
eISSN - 1089-7550
pISSN - 0021-8979
DOI - 10.1063/1.5116369
Subject(s) - bismuth , materials science , thermoelectric materials , thermoelectric effect , electrical resistivity and conductivity , doping , crystallite , condensed matter physics , thermal conductivity , semimetal , seebeck coefficient , thermal conduction , crystal structure , electronic structure , chemical physics , nanotechnology , thermodynamics , optoelectronics , crystallography , chemistry , composite material , metallurgy , silicon , physics , quantum mechanics
Temperature-dependent transport properties of the recently discovered layered bismuth-rich tellurobromides Bi n TeBr (n = 2, 3) are investigated for the first time. Dense homogeneous polycrystalline specimens prepared for different electrical and thermal measurements were synthesized by a ball milling-based process. While the calculated electronic structure classifies Bi 2 TeBr as a semimetal with a small electron pocket, its transport properties demonstrate a semiconductorlike behavior. Additional bismuth bilayers in the Bi 3 TeBr crystal structure strengthens the interlayer chemical bonding thus leading to metallic conduction. The thermal conductivity of the semiconducting compositions is low, and the electrical properties are sensitive to doping with a factor of four reduction in resistivity observed at room temperature for only 3% Pb doping. Investigation of the thermoelectric properties suggests that optimization for thermoelectrics may depend on particular elemental substitution. The results presented are intended to expand on the research into tellurohalides in order to further advance the fundamental investigation of these materials, as well as investigate their potential for thermoelectric applications.