Visualization of nanocrystalline CuO in the grain boundaries of Cu2O thin films and effect on band bending and film resistivity
Author(s) -
Jonas Deuermeier,
Hongjun Liu,
Laëtitia Rapenne,
Tomás Calmeiro,
Gilles Renou,
Rodrigo Martins,
David MuñozRojas,
Elvira Fortunato
Publication year - 2018
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.5042046
Subject(s) - materials science , grain boundary , nanocrystalline material , band bending , thin film , schottky barrier , conductive atomic force microscopy , chemical vapor deposition , transmission electron microscopy , electrical resistivity and conductivity , optoelectronics , nanotechnology , composite material , atomic force microscopy , microstructure , diode , electrical engineering , engineering
Direct evidence for the presence of a CuO structure in the grain boundaries of Cu2O thin films by chemical vapor deposition is provided by high resolution automated phase and orientation mapping (ASTAR), which was not detectable by classical transmission electron microscopy techniques. Conductive atomic force microscopy (CAFM) revealed that the CuO causes a local loss of current rectification at the Schottky barrier between the CAFM tip and Cu2O. The suppression of CuO formation at the Cu2O grain boundaries is identified as the key strategy for future device optimization.
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