Ppb-level H2S detection for SF6 decomposition based on a fiber-amplified telecommunication diode laser and a background-gas-induced high-Q photoacoustic cell
Author(s) -
Xukun Yin,
Lei Dong,
Hongpeng Wu,
Weiguang Ma,
Lei Zhang,
Wangbao Yin,
Liantuan Xiao,
Suotang Jia,
Frank K. Tittel
Publication year - 2017
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4987008
Subject(s) - laser , gas laser , sulfur hexafluoride , diode , materials science , optics , detection limit , attenuation coefficient , resonator , optoelectronics , analytical chemistry (journal) , chemistry , physics , organic chemistry , chromatography
A ppb-level hydrogen sulfide (H2S) gas sensor for sulfur hexafluoride (SF6) decomposition analysis was developed by means of a background-gas-induced high-Q differential photoacoustic cell (PAC) and a fiber-amplified telecommunication diode laser. The watt-level excitation laser power compensates the sensitivity loss as a result of using a low cost, near-IR laser source. The differential design with a large cylindrical resonator diameter allows the PAC to accommodate the high power beam and maintain a low noise level output. The theory of background-gas-induced high-Q PAC is provided and was verified experimentally. A H2S detection limit (1σ) of 109 ppb in a SF6 buffer gas was achieved for an averaging time of 1 s, which corresponds to a normalized noise equivalent absorption coefficient of 2.9 × 10−9 cm−1 W Hz−1/2
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