Rotational excitation of the interstellar NH2 radical by H2
Author(s) -
Nezha Bouhafs,
François Lique,
Alexandre Faure,
A. Bacmann,
Jun Li,
Hua Guo
Publication year - 2017
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.4975324
Subject(s) - excitation , atomic physics , close coupling , scattering , physics , collision , collisional excitation , rotational transition , molecule , potential energy surface , rotational energy , quantum , angular momentum , ionization , quantum mechanics , ion , computer security , computer science
We present quantum close-coupling calculations for the rotational excitation of the interstellar amidogen radical NH due to collisions with H molecules. The calculations are based on a recent, high-accuracy full-dimensional NH potential energy surface adapted for rigid-rotor scattering calculations. The collisional cross section calculations are performed for all transitions among the first 15 energy levels of both ortho- and para-NH and for total energies up to 1500 cm. Both para- and ortho-H colliding partners are considered. The cross sections for collision with para- and ortho-H are found to differ significantly, the magnitude of the ortho-H ones being dominant. No strong propensity rules are observed but transitions with Δk=0 are slightly favored.
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