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Influence of surface state on hydrogen sorption by zirconium alloy Zr1Nb
Author(s) -
Viktor N. Kudiiarov,
Maria N. Babikhina,
Н. С. Пушилина,
Egor Kashkarov,
M. S. Syrtanov
Publication year - 2016
Publication title -
aip conference proceedings
Language(s) - English
Resource type - Conference proceedings
eISSN - 1551-7616
pISSN - 0094-243X
DOI - 10.1063/1.4964557
Subject(s) - zirconium , hydrogen , sorption , materials science , alloy , adsorption , zirconium alloy , nickel , inorganic chemistry , hydrogen storage , metallurgy , chemical engineering , chemistry , organic chemistry , engineering
This work is focused on the investigation of hydrogen sorption behavior by zirconium alloy Zr1Nb with different surface states. Zirconium alloy samples in initial state, after ion cleaning with subsequent nickel deposition and after treatment by Low Energy High Current Pulsed Electron Beam (LEHCPEB) were hydrogenated at constant pressure and different temperatures. Hydrogen sorption rates as well as the energy of hydrogen adsorption by zirconium alloy with different surface states have been evaluated. It was shown, that ion cleaning with subsequent nickel deposition leads to the hydrogen sorption rate increasing at temperatures 350 – 550 °C, while the energy of hydrogen adsorption by zirconium alloy reduces on 15%. Modification by LEHCPEB leads to the hydrogen sorption rate decreasing at temperatures 350 – 550 °C, while the energy of hydrogen adsorption by zirconium alloy grows on 15%

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