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Perspective: Understanding of ripening growth model for minimum residual PbI2 and its limitation in the planar perovskite solar cells
Author(s) -
SeYun Kim,
Hyo Jeong Jo,
ShiJoon Sung,
DaeHwan Kim
Publication year - 2016
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4963841
Subject(s) - ostwald ripening , perovskite (structure) , materials science , photovoltaic system , planar , energy conversion efficiency , halide , solar cell , perovskite solar cell , crystal growth , nanotechnology , engineering physics , chemical engineering , optoelectronics , inorganic chemistry , crystallography , chemistry , computer science , electrical engineering , physics , computer graphics (images) , engineering
The power conversion efficiency of lead halide perovskite solar cells recently surpassed 22.1%. In this study, we suggest the perovskite absorber growth mechanism of the two-step process could be explained by an Ostwald ripening growth model for planar-structure perovskite solar cells. We attempt to find out the source of two main problems such as unreacted PbI2 and non-uniformed morphology by the proposed ripening growth mechanism and experimental results. This growth mechanism opens the way toward understanding a key aspect of the photovoltaic operation of high-efficiency, two-step perovskite solar cells

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