Correlation between structure and oxygen ion dynamics in Y substituted La2Mo2O9 ionic conductors
Author(s) -
T. Paul,
A. Ghosh
Publication year - 2016
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.4963199
Subject(s) - ion , conductivity , dielectric , ionic bonding , ionic conductivity , oxygen , analytical chemistry (journal) , spectral line , mean squared displacement , electrical resistivity and conductivity , materials science , diffraction , x ray photoelectron spectroscopy , chemistry , nuclear magnetic resonance , molecular dynamics , physics , electrode , optics , computational chemistry , optoelectronics , organic chemistry , chromatography , astronomy , quantum mechanics , electrolyte
We have measured the ac conductivity and dielectric spectra for La2-xYxMo2O9 (0.05 ≤ x ≤ 0.20) in wide temperature and frequency ranges. We have obtained the mean square displacement and the spatial extent of nonrandom sub-diffusive regions for oxygen ions by analyzing the ac conductivity and dielectric spectra respectively. The structure of the samples has been studied using X-ray photoelectron spectra, X-ray and electron diffraction. It is observed that the composition dependence of these characteristic lengths is correlated with the distance between oxygen ions obtained from structural studies
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