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Strain development during the phase transition of La(Fe,Mn,Si)13Hz
Author(s) -
Henrique Neves Bez,
K. Nielsen,
Anders Smith,
Poul Norby,
Kenny Ståhl,
C.R.H. Bahl
Publication year - 2016
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4960358
Subject(s) - curie temperature , materials science , ferromagnetism , paramagnetism , crystallite , phase transition , atmospheric temperature range , condensed matter physics , phase (matter) , microstructure , transition temperature , analytical chemistry (journal) , crystallography , chemistry , metallurgy , thermodynamics , physics , superconductivity , organic chemistry , chromatography
We use powder X-ray diffraction to evaluate the temperature dependence of the crystalline properties during the magnetic phase transition of La(Fe,Mn,Si)13Hz as a function of the Fe/Mn/Si ratio. Both the paramagnetic and ferromagnetic phases were observed as peak overlaps in the patterns around the Curie temperature (TC) occurring continuously in a temperature range of about 5 K around TC. Using the Williamson-Hall method, we evaluate the strain developing in the crystallites during the transition and find that it is associated with the growth of the paramagnetic phase as the transition occurs. Based on our measurements and microstructure analyses, we propose that cracking during the phase transition is due to or aggravated by the small content of a La-rich phase.

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