Thermoelectric transport in surface- and antimony-doped bismuth telluride nanoplates
Author(s) -
Michael T. Pettes,
Jaehyun Kim,
Wei Wu,
Karen C. Bustillo,
Li Shi
Publication year - 2016
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4955400
Subject(s) - materials science , thermoelectric effect , bismuth telluride , seebeck coefficient , antimony , bismuth , thermoelectric materials , doping , figure of merit , thermal conductivity , atmospheric temperature range , condensed matter physics , optoelectronics , composite material , metallurgy , thermodynamics , physics
We report the in-plane thermoelectric properties of suspended (Bi1−xSbx)2Te3 nanoplates with x ranging from 0.07 to 0.95 and thicknesses ranging from 9 to 42 nm. The results presented here reveal a trend of increasing p-type behavior with increasing antimony concentration, and a maximum Seebeck coefficient and thermoelectric figure of merit at x ∼ 0.5. We additionally tuned extrinsic doping of the surface using a tetrafluoro-tetracyanoquinodimethane (F4-TCNQ) coating. The lattice thermal conductivity is found to be below that for undoped ultrathin Bi2Te3 nanoplates of comparable thickness and in the range of 0.2–0.7 W m−1 K−1 at room temperature
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