Enhanced thermoelectric properties of n-type NbCoSn half-Heusler by improving phase purity
Author(s) -
Ran He,
Lihong Huang,
Yumei Wang,
Ge. G. Samsonidze,
Boris Kozinsky,
Qinyong Zhang,
Zhifeng Ren
Publication year - 2016
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4952994
Subject(s) - materials science , thermoelectric effect , arc melting , hot pressing , ball mill , figure of merit , metallurgy , solid solution , power factor , analytical chemistry (journal) , alloy , thermodynamics , optoelectronics , power (physics) , physics , chemistry , chromatography
Here we report the thermoelectric properties of NbCoSn-based n-type half-Heuslers (HHs) that were obtained through arc melting, ball milling, and hot pressing process. With 10% Sb substitution at the Sn site, we obtained enhanced n-type properties with a maximum power factor reaching ∼35 μW cm−1 K−2 and figure of merit (ZT) value ∼0.6 in NbCoSn0.9Sb0.1. The ZT is doubled compared to the previous report. In addition, the specific power cost ($ W−1) is decreased by ∼68% comparing to HfNiSn-based n-type HH because of the elimination of Hf
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