A one-dimensional stochastic approach to the study of cyclic voltammetry with adsorption effects | Zendy

Adib J. Samin | Zendy

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A one-dimensional stochastic approach to the study of cyclic voltammetry with adsorption effects

Author(s) -

Adib J. Samin

Publication year - 2016

Publication title -

aip advances

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.421

H-Index - 58

ISSN - 2158-3226

DOI - 10.1063/1.4948698

Subject(s) - cyclic voltammetry , adsorption , random walk , mass transport , voltammetry , statistical physics , electrode , redox , materials science , kinetics , stochastic process , chemistry , thermodynamics , chemical physics , mathematics , physics , electrochemistry , statistics , inorganic chemistry , classical mechanics , engineering physics

In this study, a one-dimensional stochastic model based on the random walk approach is used to simulate cyclic voltammetry. The model takes into account mass transport, kinetics of the redox reactions, adsorption effects and changes in the morphology of the electrode. The model is shown to display the expected behavior. Furthermore, the model shows consistent qualitative agreement with a finite difference solution. This approach allows for an understanding of phenomena on a microscopic level and may be useful for analyzing qualitative features observed in experimentally recorded signals

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