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Venting temperature determines surface chemistry of magnetron sputtered TiN films
Author(s) -
Grzegorz Greczyński,
Stanislav Mráz,
Lars Hultman,
Jochen M. Schneider
Publication year - 2016
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4940974
Subject(s) - tin , x ray photoelectron spectroscopy , sputter deposition , refractory metals , sputtering , ceramic , cavity magnetron , nitride , materials science , thin film , characterization (materials science) , metallurgy , chemical engineering , chemistry , layer (electronics) , nanotechnology , engineering
Surface properties of refractory ceramic transition metal nitride thin films grown by magnetron sputtering are essential for resistance towards oxidation necessary in all modern applications. Here, typically neglected factors, including exposure to residual process gases following the growth and the venting temperature Tv, each affecting the surface chemistry, are addressed. It is demonstrated for the TiN model materials system that Tv has a substantial effect on the composition and thickness-evolution of the reacted surface layer and should therefore be reported. The phenomena are also shown to have impact on the reliable surface characterization by x-ray photoelectron spectroscopy.

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