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Increasing photon absorption and stability of PbS quantum dot solar cells using a ZnO interlayer
Author(s) -
Lai-Hung Lai,
Mark J. Speirs,
Feng-Kuei Chang,
Laura Piveteau,
Maksym V. Kovalenko,
Jen-Sue Chen,
JihJen Wu,
Maria Antonietta Loi
Publication year - 2015
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4934946
Subject(s) - materials science , quantum dot , energy conversion efficiency , optoelectronics , absorption (acoustics) , quantum efficiency , solar cell , glovebox , nanoparticle , nanotechnology , composite material , chemistry , organic chemistry
We compared PbS quantum dot (QD) solar cells with different cathode interlayer materials, namely, LiF and ZnO nanoparticles, using the same device structure. Solar cells fabricated with the ZnO interlayer gave a power conversion efficiency of 4.8%, which is higher (above the experimental variation) than the 4.1% efficiency obtained with a LiF interlayer. We found that the ZnO interlayer alters the spatial distribution of the optical field, leading to an increase in external quantum efficiency in the visible range. Furthermore, devices with ZnO as interlayer showed more stable performance than the ones using LiF, with practically no power conversion efficiency degradation after 1 month inside a N-2 glovebox. (C) 2015 AIP Publishing LLC

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