Discrimination of molecular thin films by surface-sensitive time-resolved optical spectroscopy
Author(s) -
Simone Peli,
N. Nembrini,
Francesco Damin,
Marcella Chiari,
Claudio Giannetti,
Francesco Banfi,
Gabriele Ferrini
Publication year - 2015
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4934216
Subject(s) - thin film , absorbance , materials science , spectroscopy , optoelectronics , ranging , nanotechnology , optics , computer science , physics , telecommunications , quantum mechanics
An optical discrimination technique, tailored to nanometric-sized, low optical absorbance molecular complexes adhering to thin metal films, is proposed and demonstrated. It is based on a time-resolved evanescent-wave detection scheme in conjunction with hierarchical cluster analysis and principal value decomposition. The present approach aims to differentiate among molecular films based on statistical methods, without using previous detailed knowledge of the physical mechanisms responsible for the detected signal. The technique is open to integration in lab-on-a-chip architectures and nanoscopy platforms for applications ranging from medical screening to material diagnostics
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