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Double-shelled plasmonic Ag-TiO2 hollow spheres toward visible light-active photocatalytic conversion of CO2 into solar fuel
Author(s) -
Shichao Feng,
Meng Wang,
Yong Zhou,
Ping Li,
Wenguang Tu,
Zhigang Zou
Publication year - 2015
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4930043
Subject(s) - photocatalysis , materials science , plasmon , visible spectrum , nanoparticle , chemical engineering , spheres , photochemistry , irradiation , plasmonic nanoparticles , nanotechnology , optoelectronics , catalysis , organic chemistry , chemistry , physics , astronomy , engineering , nuclear physics
Double-shelled hollow hybrid spheres consisting of plasmonic Ag and TiO2 nanoparticles were successfully synthesized through a simple reaction process. The analysis reveals that Ag nanoparticles were dispersed uniformly in the TiO2 nanoparticle shell. The plasmonic Ag-TiO2 hollow sphere proves to greatly enhance the photocatalytic activity toward reduction of CO2 into renewable hydrocarbon fuel (CH4) in the presence of water vapor under visible-light irradiation. The possible formation mechanism of the hollow sphere and related plasmon-enhanced photocatalytic performance were also briefly discussed

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