Consistent formulation of the crossover from density to velocity dependent recombination in organic solar cells

Carrier recombination is a central process in bulk heterojunction organic solar cells. Based on the competition of hopping rates that either implies escape in a broad density of states or recombination across the interface, we formulate a general theory of recombination flux that distinguishes reaction or transport limited recombination according to charge density. The Langevin picture is valid only in the low charge density limit, and a crossover to the reaction controlled regime occurs at higher densities. We present results from impedance spectroscopy of poly(3-hexylthiophene):methanofullerene solar cell that exhibit this crossoverThe work was supported by Generalitat Valenciana (Project No. ISIC/2012/008)