3C-SiC/ZnS heterostructured nanospheres with high photocatalytic activity and enhancement mechanism
Author(s) -
J. Zhang,
Xinglong Wu,
L. Z. Liu,
Lun Yang,
Zhixing Gan,
Paul K. Chu
Publication year - 2015
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.4915125
Subject(s) - photocatalysis , materials science , heterojunction , nanocrystal , visible spectrum , optoelectronics , absorption (acoustics) , wide bandgap semiconductor , nanotechnology , chemical engineering , catalysis , chemistry , composite material , biochemistry , engineering
3C-SiC/n-type ZnS heterostructured nanospheres synthesized hydrothermally deliver enhanced photocatalytic performance under visible light excitation. The heterostructured catalysts consisting of 3C-SiC and ZnS nanocrystals with a mean size being less than 5 nm exhibit extended light absorption to the visible range. The proper band structure of the 3C-SiC and ZnS nanocrystals and intrinsic electric field induced by the heterojunction promote separation of photoexcited electrons and holes in the ZnS and 3C-SiC nanocrystals resulting in the increased photocatalytic efficiency. The associated mechanism is studied and proposed
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