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Selective aerobic oxidation of 1,3-propanediol to 3-hydroxypropanoic acid using hydrotalcite supported bimetallic gold nanoparticle catalyst in water
Author(s) -
M. Shahjamali Mohammad,
Shun Nishimura,
Kohki Ebitani
Publication year - 2015
Publication title -
aip conference proceedings
Language(s) - English
Resource type - Conference proceedings
eISSN - 1551-7616
pISSN - 0094-243X
DOI - 10.1063/1.4913545
Subject(s) - hydrotalcite , bimetallic strip , catalysis , nanoparticle , selectivity , yield (engineering) , propanediol , chemistry , nuclear chemistry , inorganic chemistry , materials science , organic chemistry , nanotechnology , metallurgy
Selective oxidation of 1,3-propanediol (1,3-PD) to 3-hydroxypropanoic acid (3-HPA), an important industrialbuilding block, was successfully achieved using hydrotalcite-supported bimetallic Au nanoparticle catalysts in water at 343 K under aerobic and base-free conditions. The highest yield of 42% with 73% selectivity towards 3-HPA was afforded by 1wt%Au_0.8Pd_0.2-PVP/HT catalyst

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