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Large spectral weight transfer in optical conductivity of SrTiO3 induced by intrinsic vacancies
Author(s) -
Teguh Citra Asmara,
Xiao Renshaw Wang,
Iman Santoso,
Qinfang Zhang,
Tomonori Shirakawa,
Dongchen Qi,
A. Kotlov,
M. Motapothula,
Mark B. H. Breese,
T. Venkatesan,
Seiji Yunoki,
Michael Rübhausen,
Ariando Ariando,
Andrivo Rusydi
Publication year - 2014
Publication title -
journal of applied physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.699
H-Index - 319
eISSN - 1089-7550
pISSN - 0021-8979
DOI - 10.1063/1.4878675
Subject(s) - ultraviolet , conductivity , band gap , ellipsometry , optical conductivity , materials science , ion , range (aeronautics) , electrical resistivity and conductivity , spectral line , reflectivity , analytical chemistry (journal) , atomic physics , condensed matter physics , chemistry , optoelectronics , thin film , optics , physics , nanotechnology , organic chemistry , chromatography , astronomy , composite material , quantum mechanics
The optical conductivity (σ1) of SrTiO3 for various vacancies has been systematically studied using a combination of ultraviolet-vacuum ultraviolet reflectivity and spectroscopic ellipsometry. For cation (Ti) vacancies, σ1 shows large spectral weight transfer over a wide range of energy from as high as 35 eV to as low as 0.5 eV and the presence of mid-gap states, suggesting that strong correlations play an important role. Meanwhile, for anion (O) vacancies, σ1 shows changes from 7.4 eV up to 35 eV

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