Antiferroelectricity induced by electric field in NaNbO3-based lead-free ceramics
Author(s) -
Yonghao Xu,
Wei Hong,
Yujun Feng,
Xiaoli Tan
Publication year - 2014
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4863850
Subject(s) - antiferroelectricity , ferroelectricity , electric field , materials science , condensed matter physics , dipole , polarization (electrochemistry) , ferroelectric ceramics , phase (matter) , polarization density , crystallite , phase transition , ceramic , dielectric , optoelectronics , chemistry , physics , magnetic field , composite material , magnetization , metallurgy , organic chemistry , quantum mechanics
Electric fields are known to favor a ferroelectric phase with parallel electric dipoles over an antiferroelectric phase. We demonstrate in this Letter that electric fields can induce an antiferroelectric phase out of a ferroelectric phase in a NaNbO3-based lead-free polycrystalline ceramic. Such an unlikely ferroelectric-to-antiferroelectric phase transition occurs at fields with a reversed polarity and competes with the ferroelectric polarization reversal process.
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