Band offsets at zincblende-wurtzite GaAs nanowire sidewall surfaces
Author(s) -
Pierre Capiod,
Tengfei Xu,
J. P. Nys,
Maxime Berthe,
G. Patriarche,
L. Lymperakis,
Jörg Neugebauer,
Philippe Caroff,
Rafal E. DuninBorkowski,
Ph. Ebert,
B. Grandidier
Publication year - 2013
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4821293
Subject(s) - wurtzite crystal structure , nanowire , condensed matter physics , density functional theory , materials science , fermi level , scanning tunneling spectroscopy , scanning tunneling microscope , band gap , electronic band structure , nanotechnology , chemistry , physics , computational chemistry , quantum mechanics , zinc , metallurgy , electron
The band structure and the Fermi level pinning at clean and well-ordered sidewall surfaces of zincblende (ZB)-wurtzite (WZ) GaAs nanowires are investigated by scanning tunneling spectroscopy and density functional theory calculations. The WZ-ZB phase transition in GaAs nanowires introduces p-i junctions at the sidewall surfaces. This is caused by the presence of numerous steps, which induce a Fermi level pinning at different energies on the non-polar WZ and ZB sidewall facets.
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