Comment on “Effect of gravity on contact angle: A theoretical investigation” [J. Chem. Phys. 109, 3651 (1998)]
Author(s) -
Edgar M. Blokhuis
Publication year - 2000
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.481117
Subject(s) - contact angle , meniscus , surface (topology) , physics , optics , thermodynamics , mathematics , geometry , incidence (geometry)
In a recent theoretical analysis by Ward and Sasges [J. Chem. Phys. 109, 3651 (1998)] the experimentally observed difference in contact angle at the upper and lower meniscus in a capillary is ascribed to the height dependence of the three surface tensions that determine the contact angle through Young’s law. We argue that their analysis contains an error and that in equilibrium the contact angles should be equal.
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