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Elastic electron scattering from water vapor and ice at high momentum transfer
Author(s) -
M. Vos,
E. Weigold,
R. Moreh
Publication year - 2013
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.4775810
Subject(s) - kinetic energy , scattering , momentum transfer , atomic physics , electron , water vapor , spectral line , momentum (technical analysis) , elastic scattering , chemistry , materials science , physics , optics , nuclear physics , organic chemistry , finance , quantum mechanics , astronomy , economics
We compare the area, peak separation, and width of the H and O elastic peak for light and heavy water, as observed in spectra of keV electrons scattered over large angles. Peak separation is well reproduced by the theory, but the O:H area ratio is somewhat larger than expected and is equal to the O:D area ratio. Thus no anomalous scattering from H was observed. Only minor differences are observed for scattering from a gaseous or a solid target. The extracted mean kinetic energy of H and D agreed within 5% with the calculated ones for ice. For the more difficult vapor measurements agreement was on a 12% level. A preliminary attempt to extract the O kinetic energy in ice agreed within 10% with the calculated values.

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