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Growth analysis of (Ag,Cu)InSe2 thin films via real time spectroscopic ellipsometry
Author(s) -
Scott Little,
Vinayak Ranjan,
R. W. Collins,
Sylvain Marsillac
Publication year - 2012
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.4769902
Subject(s) - materials science , ellipsometry , thin film , surface roughness , characterization (materials science) , surface finish , layer (electronics) , dielectric , analytical chemistry (journal) , deposition (geology) , in situ , optics , optoelectronics , nanotechnology , composite material , chemistry , paleontology , physics , chromatography , sediment , biology , organic chemistry
In situ and ex situ characterization methods have been applied to investigate the properties of (Ag,Cu)InSe2 (ACIS) thin films. Data acquired from real time spectroscopic ellipsometry (RTSE) experiments were analyzed to extract the evolution of the nucleating, bulk, and surface roughness layer thicknesses. The evolution of these layer thicknesses suggests a transition from Volmer-Weber to Stranski-Krastanov type behavior when Cu is replaced by Ag. The complex dielectric functions of ACIS at both deposition and room temperature as a function of film composition were also extracted from the RTSE data, enabling parameterization of the alloy optical properties.

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