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A local dissipation theorem
Author(s) -
Zahra Talaei,
James C. Reid,
Debra J. Searles
Publication year - 2012
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.4768897
Subject(s) - fluctuation dissipation theorem , dissipation , fluctuation theorem , function (biology) , statistical physics , mathematics , phase (matter) , expression (computer science) , transient (computer programming) , mathematical analysis , physics , quantum mechanics , computer science , non equilibrium thermodynamics , evolutionary biology , biology , programming language , operating system
The transient time correlation function is a standard method for measuring transport properties in simulations. It represents a special case of a more general theorem, the dissipation theorem, that indirectly calculates phase function averages though the use of the dissipation function. These indi- rect averages often have significantly less statistical error than direct averages. Recently, it has been demonstrated that a local version of the fluctuation theorem can be derived with a well defined devia- tion from the global result at sufficiently low fields. Here we show that a similar local expression can be obtained for the dissipation theorem, providing a way of determining values of phase functions by monitoring the fluctuations of phase functions in a small region of the system.Full Tex

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