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Absolute cross sections for electron scattering from furan
Author(s) -
Jelena B. Maljković,
F. Blanco,
Roman Čurı́k,
G. Garcı́a,
Bratislav P. Marinković,
Aleksandar R. Milosavljević
Publication year - 2012
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.4742759
Subject(s) - absolute scale , atomic physics , elastic scattering , electron , electron scattering , scattering , dipole , range (aeronautics) , chemistry , physics , optics , materials science , nuclear physics , organic chemistry , composite material
We report results of measurements and calculations of absolute cross sections for electron scattering from furan molecules (C 4H 4O). The experimental absolute differential cross sections (DCSs) for elastic electron scattering were obtained for the incident energies from 50 eV to 300 eV and for scattering angles from 20 to 110, by using a crossed electron-target beam setup and the relative flow technique for calibration to the absolute scale. The calculations of the electron interaction cross sections are based on a corrected form of the independent-atom method, known as the screening corrected additivity rule (SCAR) procedure and using an improved quasifree absorption model. The latter calculations also account for rotational excitations in the approximation of a free electric dipole and were used to obtain elastic DCSs as well as total and integral elastic cross sections which are tabulated in the energy range from 10 to 10 000 eV. All SCAR calculated cross sections agree very well with both the present and previously published experimental results. Additionally, calculations based on the first Born approximation were performed to calculate both elastic and vibrationally inelastic DCSs for all the modes of furane, in the energy range from 50 eV to 300 eV. The ratios of the summed vibrational to elastic DCSs are presented and discussed. Finally, the present results for furan are compared with previously published elastic DCSs for the tetrahydrofuran molecule and discussed. © 2012 American Institute of Physics.American Institute of Physics#Supported by the Ministry of Education and Science of Republic of Serbia (Project No. 171020) and Spanish Ministerio de Ciencia e Innovación Project No. FIS2009-10245, and motivated by the COST Action MP1002 (Nano-IBCT). R.C. acknowledges support of the Czech Ministry of Education (Grant No. OC10046) and the Grant Agency of the Czech Republic (Grant No. P208/11/0452).Peer Reviewe

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