The J = 2 ortho levels of the v = 0 to 6 np singlet Rydberg series of molecular hydrogen revisited | Zendy

M. Glass-Maujean | Zendy; H. Schmoranzer | Zendy; I. Haar | Zendy; André Knie | Zendy; P. Reiß | Zendy; Arno Ehresmann | Zendy

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The J = 2 ortho levels of the v = 0 to 6 np singlet Rydberg series of molecular hydrogen revisited

Author(s) -

M. Glass-Maujean,

H. Schmoranzer,

I. Haar,

André Knie,

P. Reiß,

Arno Ehresmann

Publication year - 2012

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.4742311

Subject(s) - rydberg formula , singlet state , quantum defect , synchrotron radiation , hydrogen molecule , atomic physics , series (stratigraphy) , hydrogen spectral series , ab initio , physics , ab initio quantum chemistry methods , hydrogen , molecule , excited state , optics , quantum mechanics , ionization , ion , paleontology , biology

The energies and the widths of the J = 1 para levels of the v = 0 to 6 Rydberg np singlet series of molecular hydrogen with absolute intensities of the R(0) and P(2) absorption lines were measured by a high - resolution synchrotron radiation experiment and calculated through a full ab initio multichannel quantum defect theory approach. On the basis of the agreement between theory and experiment, 31 levels were either reassigned or assigned for the first time.

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