Intrinsic resonance representation of quantum mechanics
Author(s) -
M. Carioli,
Eric J. Heller,
Klaus B. Mo ller
Publication year - 1997
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.473911
Subject(s) - basis (linear algebra) , eigenvalues and eigenvectors , representation (politics) , quantum , quantum mechanics , classical mechanics , motion (physics) , statistical physics , physics , classical physics , mathematics , theoretical physics , geometry , politics , political science , law
The choice of basis states in quantum calculations can be influenced by several requirements, and sometimes a very natural basis suggests itself. However often one retreats to a “merely complete” basis, whose coefficients in the eigenstates carry little physical insight. We suggest here an optimal representation, based purely on classical mechanics. “Hidden” constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leaving the quantum effects to be isolated and included by small matrix diagonalizations. This simplifies the hierarchical structure of couplings between “zero-order” states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamilton–Jacobi equation.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom