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Defect topologies in a nematic liquid crystal near a patchy colloid
Author(s) -
Michael Melle,
Sergej Schlotthauer,
Marco G. Mazza,
Sabine H. L. Klapp,
Martin Schoen
Publication year - 2012
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.4717619
Subject(s) - liquid crystal , colloid , network topology , anchoring , perpendicular , topology (electrical circuits) , materials science , particle (ecology) , monte carlo method , physics , condensed matter physics , chemical physics , chemistry , geometry , mathematics , computer science , oceanography , structural engineering , statistics , combinatorics , geology , engineering , operating system
Using isothermal-isobaric Monte Carlo simulations we investigate defecttopologies due to a spherical colloidal particle immersed in a nematic liquid crystal.Defects arise because of the competition between the preferential orientation at the colloid's surface and the far-field director nˆ0. Considering a chemically homogeneous colloid as a special case we observe the well-known surface and saturn ring defecttopologies for weak and strong perpendicular anchoring, respectively; for homogeneous, strong parallel anchoring we find a boojum defecttopology that has been seen experimentally [see P. Poulin and D. A. Weitz, Phys. Rev. E57, 626 (1998)] but not in computer simulations. We also consider a heterogeneous, patchy colloid where the liquid-crystal molecules anchor either preferentially planar or perpendicular at the surface of the colloid. For a patchy colloid we observe a boojum ring defecttopology in agreement with recent experimental studies [see M. Conradi, M. Ravnik, M. Bele, M. Zorko, S. Žumer, and I. Muševič, Soft Matter5, 3905 (2009)]. We also observe two other novel defecttopologies that have not been reported thus far neither experimentally nor theoretically

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