Zero-kinetic-energy pulsed-field ionization spectroscopy of the a 1Δ state of SH+ (SD+) | Zendy

J. B. Milan | Zendy; W. J. Buma | Zendy; C. A. de Lange | Zendy

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Zero-kinetic-energy pulsed-field ionization spectroscopy of the a 1Δ state of SH+ (SD+)

Author(s) -

J. B. Milan,

W. J. Buma,

C. A. de Lange

Publication year - 1996

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.470848

Subject(s) - ionization , atomic physics , field desorption , excited state , rydberg state , chemistry , excitation , spectroscopy , molar ionization energies of the elements , kinetic energy , thermal ionization , ionization energy , photoionization , atmospheric pressure laser ionization , chemical ionization , rydberg formula , ion , electron ionization , physics , quantum mechanics , organic chemistry

The results of a zero‐kinetic‐energy pulsed‐field ionization study on the a 1Δ (v+=0) excited ionic state of SH+ (SD+) obtained via two‐photon excitation of the [a 1Δ]3dπ 2Φ (v′=0) Rydberg state and subsequent one‐photon pulsed‐field ionization are reported. Accurate ionization energies as well as rotational constants are obtained. A detailed comparison between the rotational branching ratios resulting from the pulsed‐field ionization process and those of a direct ionization process is made. The results elucidate the dynamics of the high‐n Rydberg states involved in pulsed‐field ionization of SH (SD).

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