Measurement of the state-specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV | Zendy

Hao Xu | Zendy; Neil Shafer-Ray | Zendy; F. Merkt | Zendy; Daniel J. Hughes | Zendy; Michael Springer | Zendy; Richard P. Tuckett | Zendy; Richard N. Zare | Zendy

Open Access

Measurement of the state-specific differential cross section for the H+D2→HD(v′=4, J′=3)+D reaction at a collision energy of 2.2 eV

Author(s) -

Hao Xu,

Neil Shafer-Ray,

F. Merkt,

Daniel J. Hughes,

Michael Springer,

Richard P. Tuckett,

Richard N. Zare

Publication year - 1995

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.470604

Subject(s) - atomic physics , ion , chemistry , ionization , photodissociation , rydberg state , kinetic energy , physics , cross section (physics) , rydberg formula , organic chemistry , photochemistry , quantum mechanics

HI and D2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm initiates the H+D2 reaction. The HD(v=4,J′=3) velocity distribution is determined by analyzing the time‐of‐flight profile of HD+ ions produced by delayed pulsed field ionization of long‐lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique).

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