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Electronic-to-vibrational energy transfer has been studied by solving numerically the close-coupling equations, in the T-shape configuration, on the two lowest electronic states of the Na-N2 system. The diabatic potential surfaces were taken from Archirel and Habitz while the interelectronic coupling was modeled by different Gaussian-type functions. Different sets of parameters for the coupling were used in order to study the final vibrational distributions of N2. Finally, partial quenching probabilities are presented and compared with previous theoretical and experimental works. © 1989 American Institute of Physics.This work was supported by the C.I.C.Y.T. under Grant No. P80272.Peer Reviewe

journal of chemical physics online/the journal of chemical physics/journal of chemical physics

Study of the electronic-to-vibrational energy transfer in the quenching process of Na*(3 2P) with N2(1Σ+g,v=0). A quantal close coupling calculation