Intensity distribution in rotational line spectra. I. Experimental results for Doppler-free S1←S transitions in benzene | Zendy

H. Sieber | Zendy; Eberhard Riedle | Zendy; H. J. Neusser | Zendy

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Intensity distribution in rotational line spectra. I. Experimental results for Doppler-free S1←S transitions in benzene

Author(s) -

H. Sieber,

Eberhard Riedle,

H. J. Neusser

Publication year - 1988

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.454803

Subject(s) - spectral line , excited state , intensity (physics) , line (geometry) , atomic physics , benzene , doppler effect , distribution (mathematics) , chemistry , emission spectrum , physics , molecular physics , optics , quantum mechanics , geometry , mathematical analysis , mathematics , organic chemistry

Completely resolved Doppler-free rotational line spectra of six vibronic two-photon bands in benzene C6 H6 and C6 D6 are presented. The excited final states possess different excess energies in S1 (1567 to 2727 cm−1 ) and are embedded in dense manifolds of background states with differing densities of states (1

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