Two-photon dissociation of vibrationally excited HD+: The inhomogeneous differential equation approach

We extend the inhomogenous‐differential‐equation (IDE) approach of Dalgarno and Lewis for a detailed study of two‐photon dissociation (TPD) of HD+ from high vibrational levels of the 1sσg electronic state. Contrary to the H+2 case, where the TPD cross sections σ(2)L are largest near TPD thresholds and decrease monotonically with increasing photon energy, the HD+ cross sections are characterized by rich resonant and interference structures. We present σ(2)L results for TPD from the initial vi =6, 8, 10, 12, 14, 16, and ji=0 levels as well as from vi=14, ji=0, 2, 4 levels for a wide range of wavelengths of linearly polarized radiation accessible by CO2 and CO lasers. It is found that while there are four TPD pathways, the channel 1sσg(vi ji)→ω 1sσg(v, j=ji±1) →ω2pσu(k, j f=j±1) dominates the two‐photon process in most of the cases we have studied. Further, the results show that σ(2)L increases rather rapidly as the initial vibrational quantum number vi increases, indicating that the hereronuclear diatomic m...