Comment on ’’Depolarized Rayleigh spectroscopy from benzonitrile’’ | Zendy

Scott L. Whittenburg | Zendy; C. H. Wang | Zendy

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Comment on ’’Depolarized Rayleigh spectroscopy from benzonitrile’’

Author(s) -

Scott L. Whittenburg,

C. H. Wang

Publication year - 1979

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.438143

Subject(s) - benzonitrile , rayleigh scattering , rotation (mathematics) , translation (biology) , deconvolution , convolution (computer science) , spectral line , spectroscopy , physics , coupling (piping) , optics , computational physics , chemistry , materials science , mathematics , computer science , quantum mechanics , artificial intelligence , geometry , biochemistry , medicinal chemistry , messenger rna , artificial neural network , metallurgy , gene

The effects of deconvolution on translation–rotation coupling parameter as measured by Rayleigh light scattering are discussed. The results of Alms and Patterson imply that the translation–rotation parameter in benzonitrile is temperature independent. This discrepancy is discussed in terms of convolution of true spectra with the instrumental spectrum. (AIP)

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