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Observation of room temperature saturated ferroelectric polarization in Dy substituted BiFeO3 ceramics
Author(s) -
Shuxia Zhang,
Lei Wang,
Yao Chen,
Dongliang Wang,
Yingbang Yao,
Yanwei Ma
Publication year - 2012
Publication title -
journal of applied physics
Language(s) - English
Resource type - Journals
eISSN - 1089-7550
pISSN - 0021-8979
DOI - 10.1063/1.3702405
Subject(s) - multiferroics , materials science , ferroelectricity , ceramic , polarization (electrochemistry) , doping , ferroelectric ceramics , sintering , hysteresis , condensed matter physics , magnetic hysteresis , dielectric , nuclear magnetic resonance , analytical chemistry (journal) , magnetization , composite material , optoelectronics , magnetic field , chemistry , physics , chromatography , quantum mechanics
High quality Bi1− x Dy x FeO3 (0 ≤ x ≤ 0.15) ceramics have been fabricated by sintering Dy-doped BiFeO3 (BFO) precursor powders at a low temperature of 780 °C. The magnetic properties of BFO were improved by the introduction of Dy on the Bi-site. More importantly, well saturated ferroelectric hysteresis loops and polarization switching currents have been observed at room temperature. A large remnant polarization (2P r) value of 62 μC/cm2 is achieved, which is the highest value reported so far for rare-earth-doped BFO ceramics. Moreover, mechanisms for improved multiferroic properties depending on chemical doping-caused structure evolutions have also been discussed

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