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Enhanced upconversion fluorescence of Er3+:ZrO2 nanocrystals induced by phase transformation
Author(s) -
Lu Liu,
Y. J. Chen,
X. L. Zhang,
Y. X. Wang,
Xiu-e Zhang,
Yinglin Song
Publication year - 2012
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.3676601
Subject(s) - monoclinic crystal system , photon upconversion , nanocrystal , materials science , fluorescence , phase (matter) , excitation , infrared , analytical chemistry (journal) , photochemistry , nanotechnology , crystallography , optoelectronics , optics , chemistry , crystal structure , doping , organic chemistry , physics , quantum mechanics
In this letter, we demonstrate for the first time a growth of monoclinic phase ZrO2 nanocrytals based on a sol-gel method, compared to the ordinary sol-gel procedure, our method decreases the synthesized temperature from ∼1000 °C to ∼800 °C. In addition, it is found that Er3+ in monoclinic phase ZrO2 nanocrystals have greatly enhanced upconversion emissions under infrared LD excitation due to its lower environmental symmetry

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