Communication: Interfacial water structure revealed by ultrafast two-dimensional surface vibrational spectroscopy
Author(s) -
Zhen Zhang,
Łukasz Piątkowski,
Huib J. Bakker,
Mischa Bonn
Publication year - 2011
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.3605657
Subject(s) - spectroscopy , ultrashort pulse , chemical physics , aqueous solution , surface (topology) , materials science , interface (matter) , surface water , chemistry , environmental science , optics , environmental engineering , gibbs isotherm , laser , physics , geometry , mathematics , quantum mechanics
Knowledge of the interfacial water structure is essential for a basic understanding of the many environmental, technological, and biophysical systems in which aqueous interfaces appear. Using ultrafast two-dimensional surface-specific vibrational spectroscopy we show that the structure of heavy water at the water-air interface displays short-lived heterogeneity and is very different from that at the water-lipid interfac
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