A proof of Clausius’ theorem for time reversible deterministic microscopic dynamics
Author(s) -
Denis J. Evans,
Stephen R. Williams,
Debra J. Searles
Publication year - 2011
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.3592531
Subject(s) - dynamics (music) , statistical physics , mathematics , computer science , calculus (dental) , physics , medicine , dentistry , acoustics
In 1854 Clausius proved the famous theorem that bears his name by assuming the second "law" of thermodynamics. In the present paper we give a proof that requires no such assumption. Our proof rests on the laws of mechanics, a T-mixing property, an ergodic consistency condition, and on the axiom of causality. Our result relies on some recently derived theorems, such as the Evans-Searles and the Crooks fluctuation theorems and the recently discovered relaxation and dissipation theorems.No Full Tex
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