Viscosity and elastic constants of amorphous Si and Ge
Author(s) -
Ann Witvrouw,
F. Spaepen
Publication year - 1993
Publication title -
journal of applied physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.699
H-Index - 319
eISSN - 1089-7550
pISSN - 0021-8979
DOI - 10.1063/1.355031
Subject(s) - amorphous solid , materials science , thermal expansion , relaxation (psychology) , thermodynamics , enthalpy , viscosity , newtonian fluid , stress relaxation , elastic modulus , chemistry , composite material , crystallography , physics , psychology , social psychology , creep
The biaxial modulus and coefficient of thermal expansion of ion‐beam‐sputtered amorphous Si and Ge thin films were determined from curvature changes induced by differential thermal expansion. Viscous flow was measured by stress relaxation and was found to be Newtonian. The viscosity increased linearly with time as a result of structural relaxation, and its isoconfigurational activation enthalpy was 1.8±0.3 and 2.6±1.3 eV for amorphous Si and Ge, respectively. An atomistic model, based on a chain reaction of broken bond rearrangements, is proposed to describe the observation.
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