Nanocheckerboard modulations in (NaNd)(MgW)O6
Author(s) -
Mark W. Licurse,
Peter K. Davies
Publication year - 2010
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3490637
Subject(s) - nand gate , supercell , impurity , crystallography , lattice (music) , modulation (music) , materials science , condensed matter physics , perovskite (structure) , superlattice , physics , chemistry , mathematics , logic gate , thunderstorm , algorithm , meteorology , acoustics , quantum mechanics
Data is presented for a complex structural and compositional modulation in the perovskite (NaNd)(MgW)O6. This modulation creates a large 14ap×14ap×2ap supercell (ap≈3.9 A is the lattice parameter of the cubic perovskite aristotype) containing ordered regions with doubled (110) d-spacings in the a-b plane separated by two-dimensional periodic antiphase boundaries and accompanied by a nanocheckerboard pattern. Faint periodic modulations in Z-contrast images suggest an associated periodic variation in composition. The presence of a sodium rich impurity implies the composition of the stable perovskite is nonstoichiometric.
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