Production of ozone and nitrogen oxides by laser filamentation
Author(s) -
Yannick Petit,
S. Henin,
Jérôme Kasparian,
JeanPierre Wolf
Publication year - 2010
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3462937
Subject(s) - filamentation , ozone , protein filament , nucleation , nitrogen , laser , chemistry , range (aeronautics) , nitrogen oxides , volume (thermodynamics) , chemical physics , molecule , materials science , analytical chemistry (journal) , inorganic chemistry , environmental chemistry , thermodynamics , optics , organic chemistry , physics , composite material , engineering , waste management , biochemistry
We have experimentally measured that laser filaments in air generate up to 1014, 3×1012, and 3×1013 molecules of O3, NO, and NO2, respectively. The corresponding local concentrations in the filament active volume are 1016, 3×1014, and 3×1015 cm−3, and allows efficient oxidative chemistry of nitrogen, resulting in concentrations of HNO3 in the parts per million range. The latter forming binary clusters with water, our results provide a plausible pathway for the efficient nucleation recently observed in laser filaments
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