Giant magnetocaloric effects by tailoring the phase transitions
Author(s) -
N. T. Trung,
L. Zhang,
L. Caron,
K.H.J. Buschow,
E. Brück
Publication year - 2010
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3399773
Subject(s) - magnetic refrigeration , orthorhombic crystal system , materials science , ferromagnetism , condensed matter physics , phase transition , phase (matter) , magnetic shape memory alloy , alloy , magnetic alloy , refrigerant , crystallography , magnetization , magnetic domain , thermodynamics , crystal structure , magnetic field , chemistry , metallurgy , physics , gas compressor , organic chemistry , quantum mechanics
The MnCoGe alloy can crystallize in either the hexagonal Ni2In- or the orthorhombic TiNiSi-type of structure. In both phases MnCoGe behaves like a typical ferromagnet with a second-order magnetic phase transition. For MnCoGeBx with B on interstitial positions, we discover a giant magnetocaloric effect associated with a single first-order magnetostructural phase transition, which can be achieved by tuning the magnetic and structural transitions to coincide. The results obtained on the MnCoGe-type alloys may be extensible to other types of magnetic materials undergoing a first-order structural transformation and can open up some possibilities for searching magnetic refrigerants for room-temperature application
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