Impact of dopant compensation on the deactivation of boron-oxygen recombination centers in crystalline silicon
Author(s) -
Bianca Lim,
AnYao Liu,
Daniel Macdonald,
Karsten Bothe,
Jan Schmidt
Publication year - 2009
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3272918
Subject(s) - boron , dopant , silicon , oxygen , doping , materials science , recombination , activation energy , dopant activation , photochemistry , chemistry , optoelectronics , biochemistry , organic chemistry , gene
The boron-oxygen recombination center responsible for the light-induced degradation of Czochralski silicon solar cells can be permanently deactivated by illumination at elevated temperature. In this study, we examine the impact of dopant compensation on the deactivation process. The experimental results show that the deactivation rate depends inversely on the total boron concentration instead of the net doping concentration, suggesting that boron is directly involved in the deactivation process. A linear dependence of the activation energy on the total boron concentration further supports this conclusion.
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