Effects of surface ligands on the charge memory characteristics of CdSe/ZnS nanocrystals in TiO2 thin film
Author(s) -
Seung-Hee Kang,
Ch. Kiran Kumar,
Zonghoon Lee,
Velimir Radmilović,
EuiTae Kim
Publication year - 2009
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3259929
Subject(s) - quantum dot , nanocrystal , materials science , colloid , thin film , surface charge , electron , layer (electronics) , nanoparticle , dipole , optoelectronics , nanotechnology , electron affinity (data page) , chemistry , molecule , physics , organic chemistry , quantum mechanics
harge memory characteristics have been systematically studied based on colloidal CdSe/ZnS nanocrystal quantum dots (QDs) embedded in similar to 50 nm-thick TiO2 film. Ligand-capped QDs showed negligible electron charging effect, implying that the electron affinity of QDs was significantly decreased by surface dipole layer surrounding QDs. In contrast, the hole charging was affected by the carrier injection blocking effect of the surface ligands. Efficient electron and hole charging characteristics were realized by removing the surface ligands via H-2 plasma treatment.open4
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