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The surface activation layer of GaAs negative electron affinity photocathode activated by Cs, Li, and NF3
Author(s) -
Yun Sun,
R. E. Kirby,
Takashi Maruyama,
G. A. Mulhollan,
J. C. Bierman,
P. Pianetta
Publication year - 2009
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3257730
Subject(s) - photocathode , chemistry , layer (electronics) , electron , electron affinity (data page) , synchrotron radiation , gallium arsenide , optoelectronics , atomic physics , analytical chemistry (journal) , molecule , materials science , optics , physics , organic chemistry , chromatography , quantum mechanics
The lifetime of GaAs photocathodes can be greatly improved by introducing Li in the Cs+NF{sub 3} activation process. The surface activation layer of such photocathodes is studied by synchrotron radiation photoemission and is compared with GaAs photocathodes activated without Li. The charge distributions of N, F and Cs experience significant changes when Li is added in the activation. In addition, the presence of Li causes NF{sub x} molecules to take an orientation with F atoms on top. All these changes induced by Li hold the key for the lifetime improvement of GaAs photocathodes.

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